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Sigma-Aldrich 乙酰丙酮钒(III),≥99.9% 微量金属基准

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Sigma-Aldrich 乙酰丙酮钒(III),≥99.9% 微量金属基准

Sigma-Aldrich Vanadium(III) acetylacetonate,≥99.9% trace metals basis
SIGMA-ALDRICH授权代理化学试剂
CAS 号 13476-99-8品牌 Sigma-Aldrich类目 实验室试剂 / 化学试剂更新日期 2026-10-26

规格与货号

货号包装规格操作
945625-100G100 g
945625-500G500 g

产品概述

乙酰丙酮钒(III),V(acac)Al 2 O3是一种棕色至深棕色固体,极易溶于有机溶剂。我们的高纯度产品,痕量金属含量≥ 99.9%,专为使用化学气相沉积(CVD)方法沉积钒薄膜而设计。其卓越的纯度保证了杂质不会影响所得薄膜的性能,使其成为先进应用的可靠选择。此外,杂质含量极低,对催化反应的反应性、寿命和选择性有显著影响。因此,我们的乙酰丙酮钒(III),杂质含量低,是确保各种催化过程中最佳催化活性和效率的理想选择。

应用领域

Vanadium(III) acetylacetonate, ≥99.9 % trace metals basis is a suitable precursor for advance applications to improve performances. It Can be used as In Redox Flow Batteries (RFB), the V(acac)₃ system acts as a non-aqueouslectrolyte with a formal cell potential of 2.2 V. This potential arises from the single-electron disproportionation of V(acac)₃, involving redox reactions at both electrodes: the V(III)/V(II) couple at the negative electrode and the V(III)/V(IV) couple at the positive electrode. Together, these reactions highlight the efficiency of V(acac)₃ in energy storage. Our V(acac)₃, with a purity of ≥99.9% trace metals basis and low impurities, is an excellent choice for a non-aqueous electrolyte in Redox Flow Batteries (RFB). As a bifunctional soluble catalyst for Li–O₂ batteries. It interacts with a highly active superoxide intermediate, enhancing electron transport in the electrolyte. This improves reaction kinetics and minimizes side reactions. Cells using V(acac)₃ as a catalyst show high rate performance, low overpotential, and long cycle life. PMID 31298453Our V(acac)₃, with a purity of ≥99.9% trace metals basis, can further enhance these reactions by ensuring low impurities and optimal performance. As a precursor in a solvothermal low-temperature method to synthesize Na₃(VO₁−ₓPO₄)₂F₁+₂ₓ nanoparticles. The resulting Na₃(VOPO₄)₂F demonstrates excellent sodium storage performance, achieving high rate capability (up to 10 C) and long cycle stability over 1200 cycles. PMID 26179243Our Vanadium(III) Acetylacetonate, with a purity of ≥99.9% trace metals basis, can enhance these reactions by providing low impurities for optimal performance. As a precursor for synthesizing vanadium-containing compounds like TiVO₄ photoanodes, V(acac)₃, with a purity of ≥99.9% trace metals basis, plays a crucial role in forming high-quality films. The introduction of cobalt nanoparticles (Co NPs) into TiVO₄ photoanodes enhances their performance and absorption spectra, with improvements dependent on the amount of cobalt used. Additionally, incorporating Co²⁺ ions into the solution further boosts the TiVO₄ photoanode′s efficiency by reducing recombination rates and facilitating electron transfer. The high purity contributes to the formation of uniform and high-quality films, crucial for effective photoanode performance in solar energy applications.

产品特点

高纯度(≥99.9%)有助于形成均匀和高质量的薄膜,这对有效的半导体应用至关重要。对纯度和杂质的精确控制对合成材料的结晶度、形态和功能特性产生积极影响。

技术规格

英文名称Vanadium(III) acetylacetonate
CAS 号13476-99-8
线性分子式V(C5H7O2)3
经验分子式C15H21O6V
分子量348.27
MDL 号MFCD00000033
InChI keyJTPOGAMSYINTGF-LNTINUHCSA-K
InChI1S/3C5H8O2.V/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;
SMILES字符串CC(=O)\C=C(\C)O[V](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
含量测定(KMNO 4(% V),滴定法); ≥99.9%痕量金属
形态粉末或晶体
杂质≤1000 ppm痕量金属(基于
颜色绿色
熔点 181-184 °C(lit.); 181-184 °C
阳离子痕量(32 种元素)
应用电池制造
质量等级200
包装规格(货号 945625-100G)—
包装规格(货号 945625-500G)—

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可以。如 1.2300.1001,输入 12300 或 123001001 均可检索。

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