![Sigma-Aldrich Exo-2-Naphthyl Kwon [2.2.1] Bicyclic Phosphine](/img/sigma/112104-1.webp)
| 货号 | 包装规格 | 操作 |
|---|---|---|
| 798347-100MG | 100 mg |
The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.
Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-Pyrrolines
Technology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from Hydroxyproline
Aldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations
| 英文名称 | Exo-2-Naphthyl Kwon [2.2.1] Bicyclic Phosphine |
| 经验分子式 | C22H22NO2PS |
| 分子量 | 395.45 |
| MDL 号 | MFCD28016353 |
| UNSPSC | 12352000 |
| NACRES | NA.22 |
| SMILES字符串 | O=S(N1C[C@H]2[P@](C3=CC=C4C(C=CC=C4)=C3)C[C@@H]1C2)(C5=CC=C(C)C=C5)=O |
| InChI | 1S/C22H22NO2PS/c1-16-6-10-22（11-7-16）27（24，25）23-14- 2,1 -13-19（23）15-26（2,1）20-9-8-17-4-2-3-5-18（17）12-20/h2-12，19，2, 1H，13-15H2，1H3 |
| InChI key | SJQXCVUHXMHJMD-UHFFFAOYSA-N |
| 形态 | 粉末 |
| 熔点 | 153-158 °C |
| 官能团 | 膦;磺酰胺 |
| 储存温度 | 2-8°C |
| 质量等级 | 100 |
| 包装规格（货号 798347-100MG） | 100 mg |
