![Sigma-Aldrich Endo-4-Methoxyphenyl Kwon [2.2.1] Bicyclic Phosphine](/img/sigma/112526-1.webp)
| 货号 | 包装规格 | 操作 |
|---|---|---|
| 798444-100MG | 100 mg |
The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.
Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-Pyrrolines
Technology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from Hydroxyproline
Aldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations
| 英文名称 | Endo-4-Methoxyphenyl Kwon [2.2.1] Bicyclic Phosphine |
| 经验分子式 | C19H22NO3PS |
| 分子量 | 375.42 |
| MDL 号 | MFCD28016352 |
| UNSPSC | 12352005 |
| NACRES | NA.22 |
| SMILES字符串 | O=S(N1C[C@H]2[P@@](C3=CC=C(OC)C=C3)C[C@@H]1C2)(C4=CC=C(C)C=C4)=O |
| InChI | 1S/C19H22NO3PS/c1-14-3-9-19（10-4-14）25（21，22）20-12-18-11-15（20）13-24（18）17-7-5-16（23-2）6-8-17/h3-10，15，18H，11-13H2，1-2H3 |
| InChI key | RMFZMNUGIFSNIE-UHFFFAOYSA-N |
| 形态 | 粉末 |
| 熔点 | 156-161 °C |
| 官能团 | 膦;磺酰胺 |
| 储存温度 | 2-8°C |
| 质量等级 | 100 |
| 包装规格（货号 798444-100MG） | 100 mg |
