Sigma-Aldrich Palladium(II) chloride ChemBeads，固体

产品概述

Palladium(II) chloride (PdCl₂) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters.PMID 25208691 PdCl₂ reacts with N,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy-3-N,N-dimethylaminopropyl)dipalladium(II).PMID 12585906 Palladium dichloride, acetate and acetylacetonate in the [bmim][BF₄] or [bmim][PF₆] (where[bmim]⁺ = 1-butyl-3-methylimidazolium cation) ionic liquids have been employed for the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.PMID 21981005

应用领域

Palladium(II) chloride (PdCl₂) was used in the following studies:As catalyst for the carbonylation of organic tellurides by reaction with carbon monoxide.PMID 22582939As a catalyst along with Cu(II) for the deamination of phenethylamines to phenyl substituted pyrroles.PMID 22674537Together with PEG 300, promoted efficient Suzuki-coupling of aryl chlorides with aryl boronic acids.PMID 22674537
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

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For larger scale uses, product also available in powdered form (205885) & (520659)

钯催化交叉偶联反应应用指南用于合成半导体含金属聚合物，其中聚吡咯主链具有最小构象能量，并且几乎是平面的。

其他说明

利用涂覆在玻璃珠上的纳摩尔固体试剂进行高吞吐量反应筛选使用化学涂覆珠分配亚毫克级固体的多种方法用于高吞吐量实验ChemBead启用的高吞吐量交叉亲电偶联揭示了一种新的互补配体

技术规格