![Sigma-Aldrich (11bS)-N,N-二甲基-8,9,10,11,12,13,14,15-八氢二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-胺](/img/sigma/113084-1.webp)
| 货号 | 包装规格 | 操作 |
|---|---|---|
| 685569-100MG | 100 mg |
(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine is a monodentate phosphoramidite (MonoPhos) chiral ligand that can be used:
In the Cu-catalyzed synthesis of chiral 3-(arylbut-1-yn-1-yl)silane derivatives by reacting N-tosylhydrazones with silyl-substituted alkynes via asymmetric insertion.In the Rh-catalyzed asymmetric hydrogenation of R-isopropylcinnamic acid derivative, a key intermediate of renin inhibitor aliskiren.In the Rh-catalyzed conjugate addition of arylboronic acids to lactones, enones, and nitroalkenes.
DSM MonoPhos系列高效双链配体
| 英文名称 | (11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine |
| CAS 号 | 389130-06-7 |
| 经验分子式 | C22H26NO2P |
| 分子量 | 367.42 |
| NACRES | NA.22 |
| UNSPSC | 12352005 |
| MDL 号 | MFCD04117692 |
| InChI | 1S/C22H26NO2P/c1-23（2）26-24-19-13-11-15-7-3-5-9-17（15）21（19）22-18-10-6-4-8-16（18）12-14-20（22）25-26/h11-14H，3-10H2，1-2H3 |
| SMILES字符串 | CN（C）P1Oc2ccc3CCCCc3c2-c4c（O1）ccc5CCCCc45 |
| InChI key | OIZQADYWBXZQKE-UHFFFAOYSA-N |
| 形态 | 固体 |
| 光学活性 | [α]22/D 282.0°, c = 1 in chloroform |
| 熔点 | 86-94 °C |
| 官能团 | 胺 |
| 质量等级 | 100 |
| 包装规格（货号 685569-100MG） | 100 mg |
