![Sigma-Aldrich Exo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine](/img/sigma/116058-1.webp)
| 货号 | 包装规格 | 操作 |
|---|---|---|
| 798339-100MG | 100 mg |
The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.
Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-Pyrrolines
Technology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from Hydroxyproline
Aldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations
| 英文名称 | Exo-1-Naphthyl Kwon [2.2.1] Bicyclic Phosphine |
| 经验分子式 | C22H22NO2PS |
| 分子量 | 395.45 |
| NACRES | NA.22 |
| UNSPSC | 12352005 |
| MDL 号 | MFCD28016349 |
| InChI | 1S/C22H22NO2PS/c1 - 16 - 9 - 11 - 20（12 - 10 - 16）27（24，25）23 - 14 - 19 - 13 - 18（23）15 - 26（19）22 - 8 - 4 - 6 - 17 - 5 - 2 - 3 - 7 - 2,1（17）22/h2 - 12，18 - 19H，13 - 15H2，1H3/t18-，19-，26？/m0/s1 |
| SMILES字符串 | O=S(N1C[C@@]2([H])[P@](C3=CC=CC4=C3C=CC=C4)C[C@]1([H])C2)(C5=CC=C(C)C=C5)=O |
| InChI key | RGHUOMJULXTHPX-OCOBAGFRSA-N |
| 形态 | 粉末 |
| 储存条件 | 在惰性气体下 |
| 官能团 | 膦;磺酰胺 |
| 储存温度 | 2-8°C |
| 质量等级 | 100 |
| 包装规格（货号 798339-100MG） | 100 mg |
