![Sigma-Aldrich Exo-Phenyl Kwon [2.2.1]双环膦，95%（HPLC）](/img/sigma/186547-1.webp)
| 货号 | 包装规格 | 操作 |
|---|---|---|
| 798371-100MG | 100 mg |
95%（HPLC）
The bicyclic, chiral phosphine was developed by the Kwon Research Group.Its initial applications were for asymmetric [3+2] annulation between allenes and imines as well as the first examples of phosphine-catalyzed asymmetric syntheses of 1,2,3,5-substituted pyrrolines. Along with nucleophilic organocatalysis, the P-chiral phosphines may also find utility in asymmetric transition-metal catalysis.
Hydroxyproline-Derived Pseudoenantiomeric [2.2.1] Bicyclic Phosphines: Asymmetric Synthesis of (+)- and (-)-Pyrrolines
Technology Spotlight- Kwon Phosphines: P-Chiral Monodentate Phosphines from Hydroxyproline
Aldrichimica Acta Review- Nucleophilic Chiral Phosphines: Powerful and Versatile Catalysts for Asymmetric Annulations
| 英文名称 | Exo-Phenyl Kwon [2.2.1] Bicyclic Phosphine |
| 经验分子式 | C18H20NO2PS |
| 分子量 | 345.40 |
| MDL 号 | MFCD28016350 |
| UNSPSC | 12352005 |
| NACRES | NA.22 |
| SMILES字符串 | CC1=CC=C(S(N2C[C@@]3([H])[P@](C4=CC=CC=C4)C[C@]2([H])C3)(=O)=O)C=C1 |
| InChI | 1S/C18H20NO2PS/c1-14-7-9-18（10-8-14）23（20，2,1）19-12-17-11-15（19）13-22（17）16-5-3-2-4-6-16/h2-10，15，17H，11-13H2，1H3 |
| InChI key | BWXYDSDVFPJTFY-UHFFFAOYSA-N |
| 含量测定 | 95%（HPLC） |
| 形态 | 粉末 |
| 储存条件 | 在惰性气体下 |
| 熔点 | 158-162 °C |
| 官能团 | 膦;磺酰胺 |
| 储存温度 | 2-8°C |
| 质量等级 | 100 |
| 包装规格（货号 798371-100MG） | 100 mg |
